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Facile controlled synthesis of hierarchically structured mesoporous Li4Ti5O12/C/rGO composites as high-performance anode of lithium-ion batteries

Cehuang FU, Shuiyun SHEN, Ruofei WU, Xiaohui YAN, Guofeng XIA, Junliang ZHANG

《能源前沿（英文）》 2022年 第16卷 第4期   页码 607-612 doi: 10.1007/s11708-021-0798-0

摘要： In this paper, a facile strategy is proposed to controllably synthesize mesoporous Li4Ti5O12/C nanocomposite embedded in graphene matrix as lithium-ion battery anode via the co-assembly of Li4Ti5O12 (LTO) precursor, GO, and phenolic resin. The obtained composites, which consists of a LTO core, a phenolic-resin-based carbon shell, and a porous frame constructed by rGO, can be denoted as LTO/C/rGO and presents a hierarchical structure. Owing to the advantages of the hierarchical structure, including a high surface area and a high electric conductivity, the mesoporous LTO/C/rGO composite exhibits a greatly improved rate capability as the anode material in contrast to the conventional LTO electrode.

关键词： Li4Ti5O12     phenolic-resin-based carbon     mesoporous composite     graphene    

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Electrospun porous carbon nanofibers derived from bio-based phenolic resins as free-standing electrodes

《化学科学与工程前沿（英文）》 2023年 第17卷 第5期   页码 504-515 doi: 10.1007/s11705-022-2260-1

摘要： Phenolic resins were employed to prepare electrospun porous carbon nanofibers with a high specific surface area as free-standing electrodes for high-performance supercapacitors. However, the sustainable development of conventional phenolic resin has been challenged by petroleum-based phenol and formaldehyde. Lignin with abundant phenolic hydroxyl groups is the main non-petroleum resource that can provide renewable aromatic compounds. Hence, lignin, phenol, and furfural were used to synthesize bio-based phenolic resins, and the activated carbon nanofibers were obtained by electrospinning and one-step carbonization activation. Fourier transform infrared and differential scanning calorimetry were used to characterize the structural and thermal properties. The results reveal that the apparent activation energy of the curing reaction is 89.21 kJ·mol–1 and the reaction order is 0.78. The activated carbon nanofibers show a uniform diameter, specific surface area up to 1100 m2·g–1, and total pore volume of 0.62 cm3·g–1. The electrode demonstrates a specific capacitance of 238 F·g–1 (0.1 A·g–1) and good rate capability. The symmetric supercapacitor yields a high energy density of 26.39 W·h·kg–1 at 100 W·kg–1 and an excellent capacitance retention of 98% after 10000 cycles. These results confirm that the activated carbon nanofiber from bio-based phenolic resins can be applied as electrode material for high-performance supercapacitors.

关键词： lignin     bio-based phenolic resins     electrospinning     activated carbon nanofibers     supercapacitors    

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Lignin-based polymer with high phenolic hydroxyl group content prepared by the alkyl chain bridging method

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1075-1084 doi: 10.1007/s11705-022-2272-x

摘要： Inspired by the importance of the phenolic group to the electron transporting property of hole transport materials, phenolic hydroxyl groups were introduced in lignosulfonate (LS) via the alkyl chain bridging method to prepare phenolated-lignosulfonate (PLS). The results showed that the phenolic group was boosted from 0.81 mmol∙g–1 of LS to 1.19 mmol∙g–1 of PLS. The electrochemical property results showed two oxidation peaks in the cyclic voltammogram (CV) curve of PLS, and the oxidation potential of the PLS-modified electrode decreased by 0.5 eV compared with that of LS. This result indicates that PLS is more easily oxidized than LS. Based on the excellent electron transporting property of PLS, PLS was applied as a dopant in poly(3,4-ethylenedioxythiophene) (PEDOT, called PEDOT:PLSs). PLS showed excellent dispersion properties for PEDOT. Moreover, the transmittance measurement results showed that the transmittance of PEDOT:PLSs exceeded 85% in the range of 300–800 nm. The CV results showed that the energy levels of PEDOT:PLSs could be flexibly adjusted by PLS amounts. The results indicate that the phenolic hydroxyl group of lignin can be easily boosted by the alkyl chain bridging method, and phenolated lignin-based polymers may have promising potential as dopants of PEDOT to produce hole transporting materials for different organic photovoltaic devices.

关键词： lignosulfonate     phenolic group     PEDOT:PLS     hole extract layer     energy level    

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Removal of dissolved oxygen from water using a Pd-resin based catalytic reactor

Wenxin SHI, Chongwei CUI, Liye ZHAO, Shuili YU, Xia YUN

《化学科学与工程前沿（英文）》 2009年 第3卷 第1期   页码 107-111 doi: 10.1007/s11705-009-0154-0

摘要： The removal of dissolved oxygen (DO) from water was studied experimentally in a Pd-resin base catalyst reactor using purified hydrogen gas as a reducing agent. The effects of various operating conditions, such as hydrogen and water flow rates, height of the catalytic resin bed, temperature, pH value and run time, on the removal of DO, had been studied extensively. The results shows that DO could be removed by the reactor from ppm to ppb levels at ambient temperature. Increases of temperature, H gas rate and the height of the catalytic resin were helpful to improve the DO removal rate. The change of pH value from 4 to 12 resulted in no effect on DO removal. Reaction time was the key factor to control the DO removal efficiency. Only when the reaction time was longer than 2.3 minutes under the experimental conditions, could a very low DO level be achieved.

关键词： dissolved oxygen     palladium     catalytic reactor     hydrogen     resin    

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Rapid method for on-site determination of phenolic contaminants in water using a disposable biosensor

Yuanting LI, Dawei LI, Wei SONG, Meng LI, Jie ZOU, Yitao LONG

《环境科学与工程前沿（英文）》 2012年 第6卷 第6期   页码 831-838 doi: 10.1007/s11783-012-0393-z

摘要： A disposable biosensor was fabricated using single-walled carbon nanotubes, gold nanoparticles and tyrosinase (SWCNTs-AuNPs-Tyr) modified screen-printed electrodes. The prepared biosensor was applied to the rapid determination of phenolic contaminants within 15 minutes. The SWCNTs-AuNPs-Tyr bionanocomposite sensing layer was characterized with scanning electron microscopy, electrochemical impedance spectroscopy and cyclic voltammetry methods. The characterization results revealed that SWCNTs could lead to a high loading of tyrosinase (Tyr) with the large surface area and the porous morphology, while AuNPs could retain the bioactivity of Tyr and enhance the sensitivity. The detection conditions, including working potential, pH of supporting electrolyte and the amount of Tyr were optimumed. As an example, the biosensor for catechol determination displayed a linear range of 8.0 × 10 to 2.0 × 10 mol·L with a detection limit of 4.5 × 10 mol·L (S/ = 3). This method has a rapid response time within 10 s, and shows excellent repeatability and stability. Moreover, the resulting biosensor could be disposable, low-cost, reliable and easy to carry. This kind of new Tyr biosensor provides great potential for rapid, on-site and cost-effective analysis of phenolic contaminants in environmental water samples.

关键词： on-site determination     tyrosinase biosensor     phenolic contaminants     single-walled carbon nanotubes     gold nanoparticles     screen-printed electrodes    

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Phenolic compounds removal by wet air oxidation based processes

Linbi Zhou, Hongbin Cao, Claude Descorme, Yongbing Xie

《环境科学与工程前沿（英文）》 2018年 第12卷 第1期 doi: 10.1007/s11783-017-0970-2

摘要： Wet air oxidation (WAO) and catalytic wet air oxidation (CWAO) are efficient processes to degrade organic pollutants in water. In this paper, we especially reviewed the WAO and CWAO processes for phenolic compounds degradation. It provides a comprehensive introduction to the CWAO processes that could be beneficial to the scientists entering this field of research. The influence of different reaction parameters, such as temperature, oxygen pressure, pH, stirring speed are analyzed in detail; Homogenous catalysts and heterogeneous catalysts including carbon materials, transitional metal oxides and noble metals are extensively discussed, among which Cu based catalysts and Ru catalysts were shown to be the most active. Three different kinds of the reactor implemented for the CWAO (autoclave, packed bed and membrane reactors) are illustrated and compared. To enhance the degradation efficiency and reduce the cost of the CWAO process, biological degradation can be combined to develop an integrated technology.

关键词： Wet air oxidation     Catalytic wet air oxidation     Phenolic compounds     Heterogeneous catalysts     Mechanism    

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Performance of steel bridge deck pavement structure with ultra high performance concrete based on resin

《结构与土木工程前沿（英文）》 2021年 第15卷 第4期   页码 895-904 doi: 10.1007/s11709-021-0759-z

摘要： This research investigated a pavement system on steel bridge decks that use epoxy resin (EP) bonded ultra-high performance concrete (UHPC). Through FEM analysis and static and dynamic bending fatigue tests of the composite structure, the influences of the interface of the pavement layer, reinforcement, and different paving materials on the structural performance were compared and analyzed. The results show that the resin bonded UHPC pavement structure can reduce the weld strain in the steel plate by about 32% and the relative deflection between ribs by about 52% under standard axial load conditions compared to traditional pavements. The EP bonding layer can nearly double the drawing strength of the pavement interface from 1.3 MPa, and improve the bending resistance of the UHPC structure on steel bridge decks by about 50%; the bending resistance of reinforced UHPC structures is twice that of unreinforced UHPC structure, and the dynamic deflection of the UHPC pavement structure increases exponentially with increasing fatigue load. The fatigue life is about 1.2 × 107 cycles under a fixed force of 9 kN and a dynamic deflection of 0.35 mm, which meets the requirements for fatigue performance of pavements on steel bridge decks under traffic conditions of large flow and heavy load.

关键词： steel bridge deck pavement     ultra-high-performance concrete     epoxy resin     composite structure     bending fatigue performance    

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Comparison between two commercial uranium resins and a uranyl sulphate imprinted resin based on self-assembling

LIU Yaochi, XU Wei, XU Weijian, LIU Hanmao, ZHANG Xiaowen

《化学科学与工程前沿（英文）》 2007年 第1卷 第4期   页码 327-331 doi: 10.1007/s11705-007-0059-8

摘要： In recent years, resins prepared via molecular imprinting technology have received considerable attention owing to their recognition and selective adsorption. This paper deals with the comparative investigation between a uranyl sulphate imprinted ion-exchange based on self-assembling molecular imprinting technology and two kinds of commercial uranium resins (the medium pore resin D263 and strong base resin 201×7). The studies were focused on their kinetics performance, adaptability toward pH, and performance of saturation and elution in laboratory-scale column. The results show that the imprinted ion exchange resin has the fast kinetics, high adaptability toward pH, and good adsorption and elution performance.

关键词： saturation     molecular imprinting     imprinting technology     adaptability     commercial    

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新型碳酚醛材料动静态力学性能和本构关系研究

张泰,王肖钧,王志海,郭扬,王元博

《中国工程科学》 2006年 第8卷 第5期   页码 63-68

摘要：

研究了碳纤维增强酚醛复合材料在不同温度下的动静态压缩力学性能，碳酚醛材料不但是应变率敏感材料，也是温度相关材料；提出了一个非线性粘弹性本构方程，通过对实验应力-应变曲线的拟合给出了本构方程的材料参数，讨论了温度对本构方程参数的影响；分析了材料力学行为的时温等效性，给出了不同加载条件下的时温等效曲线。

关键词： 碳酚醛     力学性能     粘弹性     本构模型     时温等效    

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Self-extinguishing and transparent epoxy resin modified by a phosphine oxide-containing bio-based derivative

Gang Tang, Ruiqing Zhao, Dan Deng, Yadong Yang, Depeng Chen, Bing Zhang, Xinliang Liu, Xiuyu Liu

《化学科学与工程前沿（英文）》 2021年 第15卷 第5期   页码 1269-1280 doi: 10.1007/s11705-021-2042-1

摘要： A phosphine oxide-containing bio-based curing agent was synthesized by addition reaction between furan derivatives and diphenylphosphine oxide. The molecular structure of the as-prepared bio-based curing agent was confirmed by Fourier transform infrared spectroscopy and nuclear magnetic resonance spectroscopy. Dynamic mechanical analysis results indicated that with the increase of bio-based curing agent content, the glass transition temperature of epoxy/bio-based curing agent composites decreased, which was related to the steric effect of diphenylphosphine oxide species that possibly hinder the curing reaction as well as the reduction in the cross-linking density by mono-functional N H. By the addition of 7.5 wt-% bio-based curing agent, the resulting epoxy composite achieved UL-94 V-0 rating, in addition to limiting oxygen index of 32.0 vol-%. With the increase of content for the bio-based curing agent, the peak of heat release rate and total heat release of the composites gradually decreased. The bio-based curing agent promoted the carbonization of the epoxy matrix, leading to higher char yield with good thermal resistance. The high-quality char layer served as an effective barrier to retard the diffusion of decomposition volatiles and oxygen between molten polymers and the flame. This study provides a renewable strategy for fabricating flame retardant and transparent epoxy thermoset.

关键词： epoxy resin     flame retardant     furan derivative     diphenylphosphine oxide    

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Control strategies for disinfection byproducts by ion exchange resin, nanofiltration and their sequential

《环境科学与工程前沿（英文）》 2023年 第17卷 第10期 doi: 10.1007/s11783-023-1725-x

摘要：

● Effects of AER adsorption and NF on DBP precursors, DBPs, and TOX were examined.

关键词： Disinfection byproducts     Control     Anion exchange resin     Nanofiltration     Cytotoxicity    

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Immobilization of laccase on organic–inorganic nanocomposites and its application in the removal of phenolic

《化学科学与工程前沿（英文）》 2023年 第17卷 第7期   页码 867-879 doi: 10.1007/s11705-022-2277-5

摘要： Polydopamine-functionalized nanosilica was synthesized using an inexpensive and easily obtainable raw material, mild reaction conditions, and simple operation. Subsequently, a flexible spacer arm was introduced by using dialdehyde starch as a cross-linking agent to bind with laccase. A high loading amount (77.8 mg∙g‒1) and activity retention (75.5%) could be achieved under the optimum immobilization conditions. Thermodynamic parameters showed that the immobilized laccase had a lower thermal deactivation rate constant and longer half-life. The enhancement of thermodynamic parameters indicated that the immobilized laccase had better thermal stability than free laccase. The residual activity of immobilized laccase remained at about 50.0% after 30 days, which was 4.0 times that of free laccase. Immobilized laccase demonstrated excellent removal of phenolic pollutants (2,4-dichlorophenol, bisphenol A, phenol, and 4-chlorophenol) and perfect reusability with 70% removal efficiency retention for 2,4-dichlorophenol after seven cycles. These results suggested that immobilized laccase possessed great reusability, improved thermal stability, and excellent storage stability. Organic–inorganic nanomaterials have a good application prospect for laccase immobilization, and the immobilized laccase of this work may provide a practical application for the removal of phenolic pollutants.

关键词： polydopamine     pollutant removal     thermodynamic     phenolic pollutants     immobilized laccase    

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Carbon-based materials for photodynamic therapy: A mini-review

Di Lu, Ran Tao, Zheng Wang

《化学科学与工程前沿（英文）》 2019年 第13卷 第2期   页码 310-323 doi: 10.1007/s11705-018-1750-7

摘要： Carbon-based materials have been extensively applied in photodynamic therapy owing to the unique optical characteristics, good biocompatibility and tunable systematic toxicity. This mini-review mainly focuses on the recent application of carbon-based materials including graphene, carbon nanotube, fullerene, corannulene, carbon dot and mesoporous carbon nanoparticle. The carbon-based materials can perform not only as photosensitizers, but also effective carriers for photosensitizers in photodynamic therapy, and its combined treatment.

关键词： photodynamic therapy     carbon-based materials     graphene     carbon nanotube     fullerene     corannulene     carbon dot     mesoporous carbon nanoparticle    

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Insights into carbon-based materials for catalytic dehydrogenation of low-carbon alkanes and ethylbenzene

《化学科学与工程前沿（英文）》 2023年 第17卷 第11期   页码 1623-1648 doi: 10.1007/s11705-023-2328-6

摘要： Direct dehydrogenation with high selectivity and oxidative dehydrogenation with low thermal limit has been regarded as promising methods to solve the increasing demands of light olefins and styrene. Metal-based catalysts have shown remarkable performance for these reactions, such as Pt, CrOx, Co, ZrOx, Zn and V. Compared with metal-based catalysts, carbon materials with stable structure, rich pore texture and large surface area, are ideal platforms as the catalysts and the supports for dehydrogenation reactions. In this review, carbon materials applied in direct dehydrogenation and oxidative dehydrogenation reactions including ordered mesoporous carbon, carbon nanodiamond, carbon nanotubes, graphene and activated carbon, are summarized. A general introduction to the dehydrogenation mechanism and active sites of carbon catalysts is briefly presented to provide a deep understanding of the carbon-based materials used in dehydrogenation reactions. The unique structure of each carbon material is presented, and the diversified synthesis methods of carbon catalysts are clarified. The approaches for promoting the catalytic activity of carbon catalysts are elaborated with respect to preparation method optimization, suitable structure design and heteroatom doping. The regeneration mechanism of carbon-based catalysts is discussed for providing guidance on catalytic performance enhancement. In addition, carbon materials as the support of metal-based catalysts contribute to exploiting the excellent catalytic performance of catalysts due to superior structural characteristics. In the end, the challenges in current research and strategies for future improvements are proposed.

关键词： carbon materials     dehydrogenation     active sites     mechanism     catalytic performance     support    

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Characterization of electrode fouling during electrochemical oxidation of phenolic pollutant

Xuefeng Liu, Shijie You, Fang Ma, Hao Zhou

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1345-7

摘要： Abstract • Electrode fouling is characterized by non-destructive characterization. • Electrode fouling is highly dependent on electrochemical process. • Active chlorine can prevent the formation of polymeric fouling film. Electrode fouling is a problem that commonly occurs during electro-oxidation water purification. This study focused on identifying the fouling behavior of Pt electrode associated with the formation of polymeric layer during electro-oxidation of phenol. The in situ electrochemical measurements and non-destructive observation of the electrode morphology were reported. The results demonstrated that the electrode fouling was highly dependent on thermodynamic process of electrode that was controlled by anode potential. At anode potential lower than 1.0 V vs SHE, the direct electro-oxidation caused the electrode fouling by the formation of polymeric film. The fouling layer decreased the electrochemically active surface area from 8.38 cm2 to 1.57 cm2, indicated by the formation of polymeric film with thickness of 2.3 mm, increase in mass growing at a rate of 3.26 μg/cm2/min. The degree to which the anode was fouled was independent of anion in the electrolyte. In comparison, at anode potential higher than 2.7 V vs SHE, the anions (e.g., chloride) could exert a major influence to the behavior of electrode fouling. The presence of chloride was shown to mitigate the fouling of electrode significantly through preventing the formation of polymeric film by active chlorine (e.g., Cl• and Cl2) produced from anodic oxidation of chloride. Since chloride is the most abundant anionic species existing in both natural and engineered water system, this study not only offers a deep insight into the mechanism of electrode fouling, but also suggests strategies for anti-fouling in the presence of chloride in electro-oxidation process.

关键词： Electro-oxidation     Electrode fouling     Polymeric film     Chloride ions    

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标题 作者 时间 类型 操作

Facile controlled synthesis of hierarchically structured mesoporous Li4Ti5O12/C/rGO composites as high-performance anode of lithium-ion batteries

Cehuang FU, Shuiyun SHEN, Ruofei WU, Xiaohui YAN, Guofeng XIA, Junliang ZHANG

期刊论文

Electrospun porous carbon nanofibers derived from bio-based phenolic resins as free-standing electrodes

期刊论文

Lignin-based polymer with high phenolic hydroxyl group content prepared by the alkyl chain bridging method

期刊论文

Removal of dissolved oxygen from water using a Pd-resin based catalytic reactor

Wenxin SHI, Chongwei CUI, Liye ZHAO, Shuili YU, Xia YUN

期刊论文

Rapid method for on-site determination of phenolic contaminants in water using a disposable biosensor

Yuanting LI, Dawei LI, Wei SONG, Meng LI, Jie ZOU, Yitao LONG

期刊论文

Phenolic compounds removal by wet air oxidation based processes

Linbi Zhou, Hongbin Cao, Claude Descorme, Yongbing Xie

期刊论文

Performance of steel bridge deck pavement structure with ultra high performance concrete based on resin

期刊论文

Comparison between two commercial uranium resins and a uranyl sulphate imprinted resin based on self-assembling

LIU Yaochi, XU Wei, XU Weijian, LIU Hanmao, ZHANG Xiaowen

期刊论文

新型碳酚醛材料动静态力学性能和本构关系研究

张泰,王肖钧,王志海,郭扬,王元博

期刊论文

Self-extinguishing and transparent epoxy resin modified by a phosphine oxide-containing bio-based derivative

Gang Tang, Ruiqing Zhao, Dan Deng, Yadong Yang, Depeng Chen, Bing Zhang, Xinliang Liu, Xiuyu Liu

期刊论文

Control strategies for disinfection byproducts by ion exchange resin, nanofiltration and their sequential

期刊论文

Immobilization of laccase on organic–inorganic nanocomposites and its application in the removal of phenolic

期刊论文

Carbon-based materials for photodynamic therapy: A mini-review

Di Lu, Ran Tao, Zheng Wang

期刊论文

Insights into carbon-based materials for catalytic dehydrogenation of low-carbon alkanes and ethylbenzene

期刊论文

Characterization of electrode fouling during electrochemical oxidation of phenolic pollutant

Xuefeng Liu, Shijie You, Fang Ma, Hao Zhou

期刊论文